Reactions of Titanium Imides and Hydrazides with Boranes
نویسندگان
چکیده
منابع مشابه
Reactions of iodine-nitrene reagents with boranes.
Reactions of the boranes (C6F5)2BR (R = C6F5, Ph, H) with the nitrene-iodine reagents XC6H4SO2N=IPh, X = Me, Cl and MeSO2N=IPh effect the insertion of nitrene into the B–C and B–H bonds affording the species (C6F5)2BN(SO2C6H4X)R (X = Me, R = C6F5 1, Ph 3, H, 4, X = Cl, 5, X = NO2, 7) and (C6F5)2BN(SO2Me)H 6).
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The chemistry of sulphone hydrazide has gained increase interest in both synthetic organic chemistry and biological fields and has considerable value. The therapeutic importance of these compounds is the attractive force to continue research in such a point. The present review covers the literature up to date for the synthesis, reactions and applications of such compounds. Keywords—Sulphone hyd...
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The palladium-catalyzed hydroarylation of N-methyl-substituted tricyclic imides was studied in order to find a new stereoselective access to a series of new exo-aryl(hetaryl)-substituted tricyclic N-methylimides.
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The [3+2] cycloadditions of N-methyl derivatives of unsaturated imides with various nitrile oxides to yield new bridged isoxazoline derivatives with potential biological activity is described.
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ژورنال
عنوان ژورنال: Organometallics
سال: 2017
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.7b00477